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7235A催化剂芳构化活性的研究——油田轻烃芳构化试验

A STUDY ON THE AROMATIZATION ACTIVITY OF 7235A CATALYST--AROMATIZATION TEST OF OILFIELD LIGH-HYDROCARBONS

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【作者】 刘路加董群武显春张逢玉

【Author】 LIU Lujia;DONG Qun;WU Xianchun;ZHANG Fengyu Dept of Petrochemical Engineering

【机构】 大庆石油学院石油化工系大庆石油学院石油化工系

【摘要】 研制出一种以HZSM—5 沸石为载体,含多种金属活性组分的7235A催化剂,对低碳烷烃有良好的芳构化活性。用油田轻烃进行芳构化反应,在常压、550℃、WHSV=0.5h ′的反应条件下,维持芳烃收率不低于40%(重量)的单程寿命为240h,平均芳烃收率为47.78%。经历9次再生并累计运转1044h,芳构化活性无明显下降,表明这是一种活性、选择性和稳定性都比较高的低碳烷烃芳构化催化剂。

【Abstract】 A new 7235A catalyst using HZSM-5 as the carrier and loading with multimetalions as the active components was prepared. It exhibited a high aromatization activityfor lower alkanes. Using oilfield light hydrocarbons as feedstock, at atmosphere 550℃and WHSV= 0. 5hr-1, the catalyst gained a one-period life of 240 hours, in which thearomatics’ yield wasn’t lower than 40% and the average aromatics’ yield was 47. 78%.After night-time regenerations and accumulative operation hours of 1044, the aromati-zation activity of 7235A catalyst hasn’t observable descent. The experimental data indi-cated that the 7235A catalyst which has higher activity, selectivity and stability, is aprospective catalyst for the aromatization of lower alkanes.

【关键词】 [低碳烷烃][沸石]芳构化
【Key words】 [alkane][zeolite]aromatization
  • 【文献出处】 大庆石油学院学报 ,Journal of Daqing Petroleum Institute , 编辑部邮箱 ,1992年04期
  • 【分类号】TE624.47
  • 【下载频次】53
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