【摘要】 以粉状白钨酸为原料,在H₂-DMSO的介质中制得了某些DMSO配位多价金属（Cu,Co,Ni,Zn,V,Pr,Nd）的十聚钨酸盐,测定了它们的红外、紫外吸收光谱、热分析及在溶液中的稳定性。更多还原

【Abstract】 The title compounds have been successfully prepared in DMSO-H2O medium from whitepowdery tungstic acid. They are DMSO coordinated decatungstates, exist as well definedcrystals: [M（Ⅰ）（DMSO）₄ （H₂O₂）]₂ [W₁₀O₃₂] （M = Cu, Zn, Co, Ni）, [（VO） （Ⅰ） （DMSO）₄（H₂O）]₂[W₁₀O₃₂] and [M（Ⅲ） （DMSO）₈]₄[W₁₀O₃₂]₃·8H₂O （M=Pr, Nd）. The results ofelemental and thermal analyes, IR and UV spectra are presented. Their stabilities in solutionshave also been examined.更多还原