【摘要】 通过元素分析、红外光谱、核磁共振谱、热重分析、晶体结构的测定以及对化合物水解产物的分析。确认合成了下列配合物: 〔η⁵-2,4-（CH₃）₂C₅H₅〕LnCl₂·3THF（Ln=Nd,Sm,Gd）, 〔η⁵-2,4-（C₃H）₂C₅H₅〕₂LnCl·THF（Ln=Nd,Sm）, 〔η⁵-2,4-（CH₃）₂C₅H₅)₃Ln（Ln=La,Sm,Gd）, (2,4-（CH₃）₂C₅H₅=2,4-二甲基戊二烯基。 THF=四氢呋喃更多还原

【Abstract】 The following complexes were prepared by reaction of anhydrous rare earth trichlorideswith[2, 4- （CH₃）₂C₅H₅]K and characterized by elmental analysis, IR, NMR, themal analysis,X-ray diffraction analysis as well as chemical analysis of the hydrolysis products: [2, 4- （CH₃）₂C₅H₅]LnCl₂·3THF （Ln = Nd, Sm, Gd）, [2, 4- （CH₃）₂C₅H₅]₂LnCl·THF （Ln = Nd, Sm）, [2, 4- （CH₃）₂C₅H₅]₃Ln （Ln = La, Sm, Gd）, （2, 4- （CH₃）₂C₅H₅ = 2, 4 - dimethylpentadienyl; THF = tetrahydrofuran）. The complexes are soluble in THF and insoluble in petrolum ether. They are moisture-and air-sensitive.更多还原