节点文献
吡唑啉衍生物的电荷转移性能
CHARGE TRANSFER PROPERTY OF PYRAZOLINE DERIVATIVES
【摘要】 本文研究15种吡唑啉衍生物与三硝基苯等5种电子受体的电荷转移配合作用。用光谱法测定了各吡唑啉的VCT,进而由Mulliken公式求出它们的电离势(ID),另用循环伏安法测得其氧化电位(Epa)。结果表明ID与Epa线性相关,并且这种关系与化合物的结构有关。
【Abstract】 The charge transfer properties of fifteen pyrazoline derivatives with five electronacceptors-TNB,PMDA,CA, TCNQ and TNF-have been studied. The values of ionizationpotential of the donor, ID,were calculated from vCT obtaincd by spectral method accordingto the Mulliken’s equation. The relationship between ID, Ep2and structures of the donorswere discussed briefly.
【关键词】 吡唑啉;
电荷转移配合物;
电离势;
氧化电位;
【Key words】 pyrazoline; charge transfer complex; ionization potential; oxidation potential;
【Key words】 pyrazoline; charge transfer complex; ionization potential; oxidation potential;
【基金】 国家自然科学基金
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,1991年02期
- 【被引频次】1
- 【下载频次】47