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傅里叶变换红外光声光谱在聚合物研究中应用——Ⅰ.苧麻结构
FOURIER TRANSFORM INFRARED PHOTOACOUSTIC SPECTROSCOPY FOR POLYMER STUDY Ⅰ.THE SPECTRA OF ALKALI TREATED DEGUMMED RAMIE
【摘要】 <正> 长期以来,纤维材料需要切成细微粉末才能测得红外光谱。1981年Teramae和Tana-ka采用傅里叶变换红外光声光谱(FTIR-PAS)获得棉花及尼龙纤维的红外光声光谱图,它与常规KBr制样得到的红外光谱图一致。该法不需要复杂制样,具有快速简便、无损样品的优点,所得的光谱图便于计算。其后,有人用此法研究了各种人造纤维和天然纤维性能
【Abstract】 Forrier transform infrared photoacoustic spectroscopy for untreated and alkali treateddegummed ramie fiber were recorded. It indicated that when the alkali concentrationincreased, the intensity of band near 1430cm-1assigned to crystalline region of the fibergraually declined, but that for the band near 898cm-1 assigned to uncrystalline regiongradually inclined. When the alkali concentration was more than 9.0% (w/w), the area of898cm-1 band assigned to CH stretching vibration was near constant. Meanwhile, the alkalitreating temperature (20-80℃) and time (30-120min) appeared almost no influence.
【Key words】 Fourier transform infrared photoacoustic spectroscopy; degummed ramie; alkali treatment;
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,1991年01期
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