【摘要】 有机卤化物与CO的酮酸化反应是制备α-酮酸(酯)和α-酮酰胺的重要方法。以羰基钴或钯络合物为催化剂,利用卤代烷、卤代苯或苯乙烯基卤与CO反应,可高产率制得α-酮酸(酯)和α-酮酰胺。更多还原

【Abstract】 The ketocarboxylation of CO and organic halides is an important method for producing a-ketoacids, a-ketoesters and a-ketoamides. Taking cobalt carbonyl or palladium complex as a catalyst, CO reacted with paraffin halides, halogeno-benzene and styryl halides can highly yield a-ketoaeids (ester)and a-ketoamides.更多还原