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聚氯乙烯膜电极在蝙蝠葛碱含量测定中的应用
Use of Ion-selective PVC Membrane Electrode inDetermination of Menispermine inPharmaceutical Preparation
【摘要】 本文以聚氯乙烯(PVC)为基体,邻苯二甲酸二丁酯为增塑剂,四苯硼蝙蝠葛碱为活性物,研究了膜电极的制备方法及其性能。电极在pH 1.0~5.5之间使用时,线性范围宽且符合Nernst斜率,电极可不经预先分离直接应用于原料药和片剂含量的快速测定。
【Abstract】 The construction and performance characteristics of menispermine ion-selective electrode were described in this article. The electrode based on the ionpair complex of menispermine with TPB-Na was prepared with dibutye phtha-late as a plasticizer and PVC as a backbone.At the pH range 1.0-5.5, the Nerns-tion response range of the electrode is wide. The electrode can be used directly in rapid determination of menispermine in pharmaceutical preparation without any pretreatment.
【关键词】 蝙蝠葛碱;
PVC膜电极;
电位测定法;
聚氯乙烯;
【Key words】 menispermine; ion-selective PVC membrane electrode, potentiome-trie titration; PVC;
【Key words】 menispermine; ion-selective PVC membrane electrode, potentiome-trie titration; PVC;
- 【文献出处】 同济医科大学学报 ,Journal of Tongji Medical University , 编辑部邮箱 ,1991年03期
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