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PMBP萃取色谱法分离钪和镧系元素及钇的研究
Study on the Separation of Lanthanide,Yttrium and Scandium with the Method of PMBP-extraction Chromatography
【摘要】 研究了 PMBP 以环己烷为稀释剂萃取钪和镥的机理,补充了有关 PMBP 萃取钪的数据.本体系中钪和镥的 pH1/2分别为2.85和2.86.对 PMBP 萃取色谱法分离钪和镧系元素及钇的条件进行了选择.该方法可应用于离子型稀土矿中微量钪的分离和分析.
【Abstract】 Mechanism of the extraction of scandium and lutetium with PMBP/ was studied in this paper,and the extraction data about scandium with PMBP were supplied.In this sys- tem,the pH1/2 of scandium and lutetium were 0. 85 and 2.86,respectively.The separation conditions of PMBP-extraction chromatography were also chosen.This method can be ap- plied to the separation and analysis of microamount of scandium in the ion-type rare earth ore.
【关键词】 1-苯基-3-甲基-4-苯甲酰基代吡唑酮[5];
钪;
镥;
稀土;
萃取色谱;
【Key words】 PMBP; scandium; lutetium; rare earths; extraction chromatography;
【Key words】 PMBP; scandium; lutetium; rare earths; extraction chromatography;
【基金】 长春应化所国家自然科学基金;沈阳化工学院青年科学基金资助
- 【文献出处】 沈阳化工学院学报 ,Journal of Shenyang Institute of Chemical Technology , 编辑部邮箱 ,1991年03期
- 【被引频次】3
- 【下载频次】105