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壁冷管式反应器的多态、稳定性及可操作性——Ⅲ.多态的实验研究

MULTIPLICITY, STABILITY AND OPERABILITY OF WALL-COOLED TUBULAR REACTORSⅢ. EXPERIMENTAL STUDIES OF MULTIPLICITY

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【作者】 曹蔚陈良恒陈敏恒袁渭康

【Author】 Cao Wei Chen Liangheng Chen Minheng Yuan Weikang (East China University of Chemical Technology) (UNILAB Research Center of Chemical Reaction Engineering)

【机构】 华东化工学院联合化学反应工程研究所华东化工学院联合化学反应工程研究所

【摘要】 本文对不同活化能、频率因子,反应物浓度和流量进行了简单一级反应的多态行为模拟计算,得到了冷却介质流量改变时着火温度和熄火温度的关系。用邻二甲苯蒸气在V2O5催化剂存在下进行氧化反应的实验研究,所得熔盐流量对多态域的影响规律与计算结果一致。

【Abstract】 Computer simulation of multiple steady-state zone is completed for a single, first-order reaction carried out in wall cooled reactors. Information obtained is concerned with ignition temperatures and extinction temperatures subject to activation energy, pre-exponential factor, reactant concentration and flow rate. Vapor phase oxidation of o-xylene over V2O5 catalysts has been taken as a reaction system for experimental verification of multiplicity zone simulation. Although the reaction is much complicated than the simple, firstorder one, measured multiplicity still reveals similar tendency comparing with the calculation.

【基金】 国家自然科学基金会资助;国家教委博士学科基金
  • 【文献出处】 石油学报(石油加工) ,Acta Petrolei Sinica(Petroleum Processing Section) , 编辑部邮箱 ,1991年02期
  • 【被引频次】1
  • 【下载频次】52
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