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铝合金在氯化铵溶液中的缓蚀研究

A STUDY OF CORROSION INHIBITION FOR ALUMINIUM AND ITS ALLOY IN NH C1 SOLUTIONS

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【作者】 柳昌义魏忠诚高金华赵世勇

【Author】 Liu Changyi, Wei Zhongcheng, Gao Jinhua and Zhao Shiyong(Dept. of Chem., Shandong University, Jinan)

【机构】 山东大学化学系山东大学化学系 1984年毕业生

【摘要】 借助于电化学方法和SEM技术研究了铝合金在氯化铵溶液中的阳极行为.所研制的铝合金较之纯铝具有明显的耐腐蚀效果,在加有少量(NH42CrO4(C2H54NBr或明胶作为缓蚀剂的NH4Cl体系中,它们的耐蚀能力更强,阳极极化下的自放电速度很低,当电流密度为ia=15~50mA/cm2时,电极效率(η)可达99%;同时电极表面的孔蚀现象受到一定的抑制,腐蚀变得更均匀.

【Abstract】 Pure aluminium and five alloy as negative electrode material have been studied by electrochemical technique and SEM observation. The results showed that the inhibition effects of these alloys in NH4Cl solutions were much better than pure Al. Al alloy electrode had a lower self-discharge rate under anodic polarization conditions and a longer wetting storage life than pure Al electrode. Its electrode efficiency was high to 99% over a range of current density from 15 to 50 mA/cm2 in 1 mol/L NH4Cl-0.001 mol/L (NH42CrO4-0.001 mol/L (C2H54NBr or 1 mol/L NH4Cl-0.2ppm gelatine solutions. The pitting corrosion of the electrode was inhibited by these inhibitors above

【关键词】 铝合金缓蚀剂负差数效应
【Key words】 aluminium alloyinhibitornegative difference effect
  • 【文献出处】 山东大学学报(自然科学版) ,Journal of Shandong University , 编辑部邮箱 ,1991年04期
  • 【被引频次】4
  • 【下载频次】76
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