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钼配合物MoO2Cl2(C4H3OCOOH)2的合成和性质
Synthesis and Properties of Molybdenum Complex MoO2Cl2 (C4H3OCOOH)2
【摘要】 使MoCl5与C4H3OCOOH在氯苯溶剂中反应,合成了新的过渡金属钼配合物MoO2Cl2(C4H3OCOOH)2。研究了该化合物的红外光谱、紫外-可见光谱、光电子能谱和电氧化还原性质,还用DTA和TG技术研究了它的热分解过程;同时讨论了上述性质与该配合物的结构之间的关系。
【Abstract】 The complex MoO2CI2(C4H3OCOOH)2 was prepared by the reaction of MoCI5 with C4H3OCOOH in chlorobenzene. The infrared and visible-ultraviolet spectra, XPS and electrochemical properties of title complex were investigated. The processes of thermal decomposition of the coordination were investigated by DTA and TG techniques.
【关键词】 钼;
过渡金属配合物;
红外光谱;
光电子能谱;
紫外-可见光谱;
热重分析;
循环伏安;
【Key words】 molybdenum; transition-metal complex; infrared spectra; XPS; visible-ultraviolet spectra; thermogravimetry ciclie voltammetry;
【Key words】 molybdenum; transition-metal complex; infrared spectra; XPS; visible-ultraviolet spectra; thermogravimetry ciclie voltammetry;
【基金】 国家自然科学基金委员会资助项目
- 【文献出处】 吉林大学自然科学学报 ,Journal of Jilin University , 编辑部邮箱 ,1991年03期
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