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苯二酚酯类液晶的合成和性能——Ⅳ.双-(对烷氧基苯甲酸)-2,3-二氯-1,4-苯二酚酯
Syntheses and Properties of Ester Liquid Crystals of Hydroquinone Ⅳ. 2,3-Dichloro-p-phenylene-bis-(ρ-alkoxybenzoate)
【摘要】 合成了正烷氧基R为C1~C10的文题化合物,并合成了中间体2,3-二氯对苯二酚,其产率比文献值提高10%。测定了这十个化合物的介电各向异性△ε、液晶相变温度和相态等,证实这类化合物是负性液晶。
【Abstract】 The title compounds (Ⅰ) whose alkoxys contain 1~10 carbon atoms were synthesized. Corresponding intermediates, 2,3-dichlorohydroquinone, was also synthesized, the yield increased by 10% as compared with the literature. By means of magnetic field method, the values of the dielectric anisotropy of (Ⅰ) were successfully determined. The result showed that some of (Ⅰ) are liquid crystals with negative dielectric anisotropy.
【关键词】 液晶;
有机合成;
2,3-二氯-1,4-苯二酚;
对苯二酚二酯;
【Key words】 liquid crystal; organic synthesis; 2, 3-dichlorohydrcquinone; hydroquinone diester;
【Key words】 liquid crystal; organic synthesis; 2, 3-dichlorohydrcquinone; hydroquinone diester;
【基金】 国家自然科学基金
- 【文献出处】 华东化工学院学报 , 编辑部邮箱 ,1991年06期
- 【分类号】O743.5;O621.3;TQ
- 【被引频次】2
- 【下载频次】71