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FeCl3溶液浸取辉锑矿工艺过程的研究——Ⅱ.浸取动力学

Study on the Leaching Process of Stibnite in Ferric Chloride Solution Ⅱ. Leaching Kinetics

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【作者】 柳巧越孙文粹朱炳辰

【Author】 Liu Qiaoyue, Sun Wencui and Zhu Bingchen(Dept. of Chemical Engineering)

【机构】 华东化工学院化学工程系华东化工学院化学工程系华东化工学院化学工程系 天津化工研究院

【摘要】 在60~100℃、粒径180μm~55μm、FeCl3溶液浓度0.5~2.0 mol/L范围内,研究了辉锑矿的浸取动力学,并获得了动力学参数。浸取反应的表观活化能为67 kJ/mol,反应速率对CFeCl3来说是2/3级。浸取反应为化学反应控制。

【Abstract】 Effects of temperature, size, and concentration of FeCl3 on leaching rate of stibnite were observed respectively. Kinetics of leaching stibnite was studied at temperature ranging from 60℃ to 100℃, ferric chloride concentration from 0.5 to 2.0 mol/L, and size from 55μm to 180μm. The kinetic parameters were obtained. The leaching rate can be expressed by shriking-core model. The apparent activation energy of this leaching reaction is 67 kJ/mol. The order of leaching reaction rate for ferric chloride is 2/3. This leaching process is controlled by chemical reaction.

  • 【分类号】TF 803.21;TF 818
  • 【被引频次】8
  • 【下载频次】94
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