节点文献
半水煤气甲烷化耐硫催化剂的研制及其本征动力学的测试
Sulfur-Tolerant Semi-Water Gas Methanation Catalyst and Its Intrinsic Kinetics
【摘要】 本文叙述了所研制的半水煤气甲烷化耐硫催化剂所具有的物化特征.活性温度范围400~550℃,压力不小于0.6MPa,原料气中硫含量500~5000ppm(mol),空速1000h-1左右,一氧化碳转化率约为40%,其本征动力学方程dNCH4/dw=1.120×10-6exp(-7.788×104/RT)P1.13yH2O0.4yCO0.73dNCO2/dw=1.767×10-7exp(-7.423×104/RT)P1.39yCO0.16yH2O1.23(1-β)
【Abstract】 The physical and chemical characteristics of a sulfur-tolerant semi-water gas methanation catalyst, developed by the authors are described. The range of reaction temperature is 400-550℃. The pressure is no smaller than 0.6MPa. The sulfur content in the raw gas is in the range of 500-5000ppm(mol). The space velocity is about 1000h-1. The conversion of carbon monooxide is about 40%. The intrinsic kinetics equations are as follows:
- 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,1991年01期
- 【被引频次】9
- 【下载频次】177