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合成金刚石与合成体系之关系
RELATIONS OF DIAMOND SYNTHESIS WITH THE SYNTHESIZING SYSTEM
【摘要】 通过各种材料的试验和压机设备因素的测定,总结了金刚石生长过程的特性:金刚石晶体是在石墨(G)-触媒(Me)界面上生长;因电阻TG>RMe、温度TG>TMe以及与外界热交换等原因,使合成腔内产生压力、温度梯度,成为金刚石生长之驱动力。梯度过大过小对金刚石生长均不利;金刚石晶体在G-Me界面两侧是非对称性生长;每个晶粒表面有一特殊结构约20μm左右厚的金属薄膜,它起到运载碳源和催化的双重作用。要合成粗粒高强金刚石,需要有一个稳定的合成体系。本文分析了该体系状态的性质及稳定的必要性与稳定的具体方法。
【Abstract】 After studing various material behavior in the diamond synthesis processes and by measuring the factors in the HP/HT apparatus, we summerized the characteristics of diamond growth as follows :diamond grows on the graphite (G)-metal catalyst (Me) material interfaces. Since the rasistance R(G)>R(Me),temperature T(G)>T(Me) and the heat exchange with outside,et al. ,the pressure and temperature gradients thus created in the cell will become the driving force of diamond growth. Too large or too small a driving force will be harmful to diamond growth. On the surface of each diamond crystal grain,there is a thin metallic layer of thickness about 15 -20μm. This metalic thin film can both act as the carbon carrier as well as the catalyst. The growth of a coarse grain of high-strength diamond requires a stable synthesis system. The paper analysed the property of such a system and proposed a way to establish the system.
- 【文献出处】 高压物理学报 ,Chinese Journal of High Pressure Physics , 编辑部邮箱 ,1991年03期
- 【被引频次】3
- 【下载频次】36