节点文献
乳酸与乙醇酯化反应动力学
The Reaction Kinetics of Esterification on Lactic Acid with Ethanol
【摘要】 通过对实验结果的分析.得出如下结论:在硫酸催化条件下,乳酸与乙醇酯化反应是一个对歧反应,其方程为-dc/dt=k_+c~2-K_-.其中k_+,k_-为酯化、水解速度常数.由此说明酯化反应为二级反应,水解反应为零级反应.
【Abstract】 The conclusion is obtained by analysing the experimental result. The reac- tion of esterification on lactic acid with ethanol is an opposing reaction H2SO4 is used for catalyst. Which kinetic equation may be written: -dr/dt= k+c2-k-,where k+ and k- are rate constants in the esterification and hydrolysis reactions, respectively, so that the esterification is second-order reaction, and the hydrolysis is zero-order reaction.
- 【文献出处】 广西大学学报(自然科学版) ,Journal of Guangxi Univeristy(Natural Science Edition) , 编辑部邮箱 ,1991年01期
- 【被引频次】5
- 【下载频次】179