【摘要】 本文用改进的Rose平衡釜测定了甲醇-氯苯体系(760 mmHg)及氯苯-二甲基亚砜体系(100 mmHs)的汽-液平衡数据。用Herrington方法对实验数据进行了热力学一致性检验,并用Wilson活度系数方程进行了关联计算,得到相应的能量参数。实验和计算结果可作为该溶剂体系分离过程设计的依据。更多还原

【Abstract】 Vapor-Liquid equilibrium data for methanol-chlorobenzene system (760 mmHg) and chlorobenzene-dimethyl sulfoxide system (100 mmHg) were determined with modified RoseWilliams still. The experimental data were tested for thermodynamic consistency by means of Herrington method. Wilson’s equation was used to correlate the experimental data.更多还原