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PHASE EQUILIBRIUM FOR THE TERNARY SYSTEM VINYL CHLORIDE-CHLORINATED POLYETHYLENE-POLY(VINYL CHLORIDE)

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【作者】 楼剑锋翁志学黄志明潘祖仁

【Author】 LOU Jianfeng WENG Zhixue HUANG Zhiming PAN Zuren (Chemical Engineering Department, Zhejiang University, Hangzhou 310027)

【机构】 Chemical Engineering DepartmentZhejiang UniversityHangzhou 310027Hangzhou 310027

【摘要】 <正> Swelling capacity of vinyl chloride (VC) in chlorinated polyethylene (CPE) with 25—40 wt% Cl at temperature 30—57℃was studied and their relationships were correlated with Langmuir and Freundlich adsorption equations. A ternary phase diagram for VC-CPE-PVC was also established. In-situ polymerization conditions of CPE-g-VC were proposed and CPE content control was analyzed for the manufacturing process of CPE-g-VC graft product based on results of phase equilibrium study.

【Abstract】 Swelling capacity of vinyl chloride (VC) in chlorinated polyethylene (CPE) with 25—40 wt% Cl at temperature 30—57℃ was studied and their relationships were correlated with Langmuir and Freundlich adsorption equations. A ternary phase diagram for VC-CPE-PVC was also established. In-situ polymerization conditions of CPE-g-VC were proposed and CPE content control was analyzed for the manufacturing process of CPE-g-VC graft product based on results of phase equilibrium study.

【基金】 This project is supported by National Natural Science Foundation of China
  • 【文献出处】 Chinese Journal of Polymer Science ,高分子科学(英文版) , 编辑部邮箱 ,1991年03期
  • 【被引频次】3
  • 【下载频次】38
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