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PMMA/PSAN共聚物混合体系不稳相分离的中、后期特征
CHARACTERISTICS OF PHASE SEPARATION IN THE INTERMEDIATE TO LATER STAGE IN PMMA/PSAN POLYMER BLEND
【摘要】 <正> The intermediate to later stage of the spinodal decomposition of off-critical mixture of poly (methyl methacryate) ( PMMA ) and poly ( styrene-co-acryonitrile ) ( PSAN) was investigated by the time-resolved light-scattering technique.lt is shown that during unmixing process there exist power relations of maximum scattered intensity Im(t)and its corresponding wave vactor to time t. In the later stage the scaling relation of structure funcfion S (q, t) with wave vactor qm and β=3α were found. In the intermediate stage some relationship of structure function S(q,t) with wave vactor q was revealed.
【Abstract】 The intermediate to later stage of the spinodal decomposition of off-critical mixture of poly (methyl methacryate) ( PMMA ) and poly ( styrene-co-acryonitrile ) ( PSAN) was investigated by the time-resolved light-scattering technique.lt is shown that during unmixing process there exist power relations of maximum scattered intensity Im(t)and its corresponding wave vactor to time t. In the later stage the scaling relation of structure funcfion S (q, t) with wave vactor qm and β=3α were found. In the intermediate stage some relationship of structure function S(q,t) with wave vactor q was revealed.
【Key words】 PMMA; PSAN; phase separation in the intermediate; structure function.;
- 【文献出处】 高分子材料科学与工程 ,Polymeric Materials Science & Engineering , 编辑部邮箱 ,1991年02期
- 【被引频次】3
- 【下载频次】51