【摘要】 首次研究了铝铁合金溴化物的合成及其对直链烷烃异构化反应的催化作用,讨论了正戊烷的异构化反应,得到其动力学方程为1nC/C₀=-0.50t,表观活化能为26.3 kJ/moJ,测定了正己烷、正庚烷、正辛烷在不同溶剂中、不同温度下催化异构化反应的动力学曲线,为铝铁合金溴化物的工业应用提供了理论依据。更多还原

【Abstract】 The synthesis of the aluminium titanium alloy bromide and its catalysis of the isomerizatu reaction of alkane were studied for the first time. The isomerization reaction of n-pentane catalyzed by aluminium titanium alloy bromide was discussed in detail. Its kinetic equation is InC/C0= - 0. 50 t at 0℃.The apparent activation energy is 26. 3 kJ/mol. The kinetic curves of the isomerization reaction of n-hexane, n-heptane, n-octane over the catalyst in different solvents at different temperatures were determined and drawn to afford a theoretical foundation for industrial application.更多还原