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多波长系数倍率差值分光光度法的研究与应用

A Spectrophotometric Method Based on Difference of Absorption Coefficient Ratios at Multi-Wavelength and Its Application

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【作者】 李志良李梦龙俞汝勤钱锋石乐明

【Author】 Li Zhiliang Li Menglong Yu Ruqin Qian Feng Shi Leming (Department of Chemistry and Chemical Engineering,Hunan University,Changsha,410082)

【机构】 湖南大学化学化工系北京分析仪器厂北京分析仪器厂 长沙410082长沙

【摘要】 本文研究了一种新的多组分光光度测定方法即多波长吸光系数倍率差值分光光度法,该法将系数倍率法与多波长数据相结合,可消除共存组分的干扰而选择性地测定待分析物。用于复方雷琐辛涂剂中间苯二酚的测定,苯酚的干扰被消除而毋需任何分离。

【Abstract】 A new spectrophotometric method was proposed based on the difference of absor- ptivity coefficient ratios at multi-wavelength.This method was extended from K-ratio dual-wavelength spectrophotometry when combined with multi-wavelength measurements and was employed to estimate the analyte concentration and to eliminate the interference effect,The developed method was applied to assay of resorcinol in mixtures with phenol and in compound during pharmaceutical preparations with no separation.

【基金】 国家自然科学基金资助课题
  • 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1991年10期
  • 【被引频次】5
  • 【下载频次】43
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