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用挤出物胀大等方法测量聚合物熔体的第一法向应力差

Determination of the First Normal Stress Difference of Polymer Melts

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【作者】 刘颖; 陈栋荣; 潘碧莲; 苑会林;

【Author】 Liu Ying T.W. Chan Pan Bilian Yuan Huilin (Department of Polymer Science)

【机构】 北京化工学院高分子系; 北京化工学院高分子系;

【摘要】 在挤出机上安装自行设计的毛细管口模,对PP,HDPE和PS熔体采用挤出物胀大法在较高剪切速率下测量第一法向应力差N1,发现:由于N1受胀大比B和剪切应力τW的双重影响,因此弹性测试比粘性测试所需的毛细管口模长径比要大;将挤出物胀大法与其他测量N1的方法进行综合的分析比较,结果表明,挤出物胀大法所测N1值比较合理,并可满足一般工程计算的要求。

【Abstract】 The method of extrudate swell is used to determine the first normal stress difference N1 of polymer melts at high shear rates. It is found that a longer die than that used in viscosity measurements is required for the determination of N1, since N1 depends on both the swelling ratio and the shear stress. The N1 results obtained from the method of extrudate swell are compared with the results obtained by other means. It is concluded that the N1 results obtained from extrudate swell measurements are as good as anything else, and is certainly good enough for engineering purposes.

  • 【文献出处】 北京化工学院学报(自然科学版) , 编辑部邮箱 ,1991年01期
  • 【被引频次】6
  • 【下载频次】170
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