【摘要】 本文用 TEA CO₂激光器9.6R（14）支作激光光源,研究了甲氧乙醇、乙氧基乙醇和丁氧基乙醇的红外激光解离,给出了解离率与自身压力、激光脉冲数和缓冲气体压力等的关系。实验结果表明,乙氧基乙醇和丁氧基乙醇为二级反应,三者均无瓶颈效应。更多还原

【Abstract】 The infrared multiphoton dissociation of methyl cellosolve,ethyl cellosolve andbutyl cellosolve have been studied by using a TEA CO₂ laser.The dissociation probability as afunction of the sample pressure,the number of laser pulses and the pressure of inert gas havebeen determined.It is found that the IRMPD of ethyl celliosolve and butyl cellesolve are secondreaction.They haven’t the bottleneck effect.更多还原