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某些硫代磷酸酯化合物的负离子电子轰击质谱(NIEI-MS)
THE NEGATIVE ION ELECTRON IMPACT MASS SPECTRA OF SOME PHOSPHONQTHIONATES
【摘要】 本文应用低分辨负离子电子轰击质谱及亚稳分析数据,研究了10种硫代磷酯酸化合物的负离子质谱特征,探讨了其碎裂规律。指出取代基的性质及其位置对分子异构化重排有明显影响。
【Abstract】 The negative ion electron impact mass spectra (NIEJ-MS) and their cleavage in somephosphonothionates were discussed on the basis of low resolution mass spctral and meta-stable ion analysis. It is found that the property and the position of the substituentshave a marked influence on the isomeric rearrangement of the phosphonothionate.
【关键词】 硫代磷酸酯;
负离子电子轰击质谱;
分子异构化重排;
【Key words】 phosphonothionate; negative ion electron impact mass spectra; isomeric rearangement;
【Key words】 phosphonothionate; negative ion electron impact mass spectra; isomeric rearangement;
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,1990年01期
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