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FLUORIDE GLASSES CONTAINING RARE EARTH

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【作者】 张克立; 夏幽兰; 袁启华;

【Author】 Zhang Keli Xia Youlan Yuan Qihua (Department of Chemistry,Wuhan University,Wuhan 430072,China)

【机构】 Department of Chemistry Wuhan University; Wuhan 430072; China; Department of Chemistry; Wuhan University;

【摘要】 <正> Fluoride glasses containing rare earths exhibit interesting spectroscopic properties.They have widetransmission range from 0.25μm in the UV to 7μm in the IR,allowing observation,in a vitreous material,ofabsorption and emission bands in a large optical range.The absorption spectra of fluoride glasses with rareearth substitutions are found to vary with the rare earth ions used.The T_g~’s for these glasses average out at311℃.Optical properties,such as refractive indices are not obviously influenced by rare earth substitutions.

【Abstract】 Fluoride glasses containing rare earths exhibit interesting spectroscopic properties.They have wide transmission range from 0.25μm in the UV to 7μm in the IR,allowing observation,in a vitreous material,of absorption and emission bands in a large optical range.The absorption spectra of fluoride glasses with rare earth substitutions are found to vary with the rare earth ions used.The T_g~’s for these glasses average out at 311℃.Optical properties,such as refractive indices are not obviously influenced by rare earth substitutions.

【关键词】 glasses; bands; spectroscopic; fluoride; refractive; visible; Electron; indices; transitions; preparing;
  • 【文献出处】 Journal of the Chinese Rare Earth Society(English Edition) ,稀土学报(英文版) , 编辑部邮箱 ,1990年04期
  • 【下载频次】6
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