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三溴化三乙基苄铵对于苯偶姻的氧化反应
Oxidation of Benzoins by Triethylbenzylammonium Tribromide
【摘要】 <正> 作者前曾报道,三溴化三乙基苄铵(PhCH2Et3NBr3-,TEBABr3,1)和三碘化三乙基苄铵(TEBAL3)能作为有效的溴代和碘代试剂而与芳胺反应,以高产率生成多溴代和多碘代芳胺。在进一步对TEBABr3在有机合成
【Abstract】 A catalytic oxidation involving the reaction of triethylbenzylammonium tribro-mide and benzoins in the presence of benzoyl peroxide is described. A variety of benzils areprepared in good yields by the title reaction. A possible reaction mechanism is proposed.
- 【文献出处】 有机化学 ,Chinese Journal of Organic cHEMISTRY , 编辑部邮箱 ,1990年04期
- 【被引频次】12
- 【下载频次】163