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氧化亚锡催化酯化反应

Esterification Catalyzed by Stannous Oxide

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【作者】 陈锚; 杨茂利; 张富强; 李宝生;

【Author】 CHEN Mao;YANG Mao-Li;ZHANG Fu-Qiang;LI Bao-Sheng Department of Chemistry, Hebei University, Baoding 071000

【机构】 河北大学化学系; 河北大学化学系 保定; 071000; 保定;

【摘要】 <正> 锡的氧化物的催化作用较少报道,较成功的有使用氧化锡与氧化铬组成的二元催化剂催化氧化,氧化亚锡催化硝基苯还原及交酯的聚合。但用于催化酯化,只有用特定方

【Abstract】 The preparation of stannous oxide with catalytic activity for esterification wasdescribed. Esters were prepared from esterification of n-butanol and n-pentanol with aceticacid, sebacic acid, citric acid, benzoic acid, salicylic acid and phthalic anhydride in the pre-sence of the catalyst. Their yield and physical constants were determined and compared withthe data reported. The mechanism of catalytic esterification by stannous oxide was suggestedand the advantage of esterification in the presence of this catalyst was discussed.

【关键词】 酯化反应; 氧化亚锡; 催化剂;
【Key words】 esterification reaction; stannnous oxide; catalyst;
  • 【文献出处】 有机化学 ,Chinese Journal of Organic cHEMISTRY , 编辑部邮箱 ,1990年01期
  • 【被引频次】23
  • 【下载频次】295
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