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高效液相色谱法应用于D-葡萄糖酸-δ-内酯的水解研究

A Study on the Hydrolysis of D-glucono-1,5-lactone by High-Performance Liquid Chromatography

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【作者】 刘允毅苏克曼朱明华郏其庚

【Author】 Liu Yunyi,Su Keman & Zhu Minghua,The Analysis and Research Center,East China University of Chemical Technology, Shanghai,Jia Qigeng,Shanghai Buresau of Chemical Industry

【机构】 华东化工学院分析测试中心上海市化工局 上海 201107上海 201107上海 201107

【摘要】 <正> D-葡萄糖酸-δ-内酯能水解生成D-葡萄糖酸及少量D-葡萄糖酸-γ-内酯,其水解反应式为:

【Abstract】 The hydrolysis of D-glucono-1,5-lactone was investigated by reversed-phase high-performance liquid chromatography.It was found that D-gluconic acid and a small amount of D-glucono-1,4-lactone were formed.The rateconstants of hydrolysis and its reverse reaction were 2.348*10-4s-1 and 8.484*10-5s-1,respectively.The equilibrium constant of the hydrolysis was 2.768.The equilibrium was reached in about 4h.The pH value of the resulting aqueous solution was 1.9.

  • 【文献出处】 色谱 ,Chinese Journal of Chromatography , 编辑部邮箱 ,1990年04期
  • 【被引频次】3
  • 【下载频次】319
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