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我国一些煤中无机相的研究

IDENTIFICATION OF MINERALS IN SOME CHINESE COALS

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【作者】 洪蕊玉冯煜荣王瑞琴余小岚■晞

【Author】 Hong Ruiyu Feng Yurong Wang Ruiqin Yu Xiaolan Liao Xi (Department of Chemistry, Zhongshan University, Guangzhou)

【机构】 中山大学化学系中山大学化学系 广州广州 广东中山化学工业公司广州广州

【摘要】 <正> 研究煤中的无机相对于煤的综合利用和了解成煤地区的地质条件都具有重要意义。Gluskoter用低温灰化法除去煤中有机物且能保留原有的无机相,给研究煤中无机相带来了很大方便;Montano等最早用用穆斯堡尔谱直接测定煤中含铁的矿物;Quentin等用低温灰化及穆斯堡尔谱学等方法研究新西兰煤中的矿物相。本文是用等

【Abstract】 Minerals in some Chinese coals have been studied. The coal samples were ground and dried, then treated by low temperature ashing(LTA) in oxygen plasma. The sample weight loss curves of differen coal against ashing time were obtained. Lignites are always difficult to be ashed and more time is required. Moessbauer spectra can be obtained from the samples with high iron content without treatment.For those samples with low iron content, the LTA treatment is necessary. Since Moessbauer parameters of Fe3+ in illte and jarosite are similar, chemical treatment, washing the low temperature ash with dilute acid, are required for differentiation. Minerals in low temperature ash were also identified by XRD method. The combination of LTA, Moessbauer spectroscopy, XRD method and chemical treatment is an effective way to identify minerals in coal.

【基金】 国家自然科学基金
  • 【文献出处】 燃料化学学报 ,Journal of Fuel Chemistry and Technology , 编辑部邮箱 ,1990年03期
  • 【下载频次】129
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