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阳离子型淀粉絮凝剂的合成及其絮凝性能—S—g—APAM的合成及性能

Syntheses and Floccu lations of Cationic Starch Flocculant——Syntheses and properties of S-g-APAM

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【作者】 杨光中; 国文华; 左丽华; 王秀珍; 崔希海; 戴晓华;

【Author】 Yang Guangzhong Guo Wenhua Zuo Lihua Wang Xiuzhen (Department of Chemistry, Tianjin University)Cui Xihai Dai Xiaohua( Hongqi Starch Plant, Tianjin)

【机构】 天津大学化学系; 天津红旗淀粉厂; 天津红旗淀粉厂;

【摘要】 本文用淀粉接枝聚丙烯酰胺(S—g—PAM)与甲醛、二甲胺反应,合成了淀粉—胺甲基化聚丙烯酰胺接枝共聚物(S—g—APAM)。研究了各种因素对胺甲基化反应的影响。对钠型膨润土的絮凝性能研究表明:S—g—APAM与S—g—PAM及聚丙烯酰胺(PAM)相比,具有良好的絮凝效果。并研究了该胺甲基化的阳离子絮凝剂水溶液的流变学性质。

【Abstract】 In this paper, the graft copolymer of starchaminomethy lated polyacry-lamide ( S-g-APAM ) was prepared by the aminomethy lation of graftcopolymer of starch- polyacry lamide (S-g-PAM) with formalinanddimethyl amine. The factors effecting the aminomethy lation wereinvestigated.On the basis of the experimental results of floccu lation on Na-type bentonite suspention,S-g-APAM is a better flocculant compared withPAM, S-g-PAM.In addition the rheology properties of the aqueous solutionof S-g-APAM were studied.

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