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邻菲啰啉与四氧嘧啶稀土化合物的合成及抑菌作用
The Synthesis and Antibacterial Property of Rare Earth Compounds with Alloxan and 1,10-Phenanthroline
【摘要】 本文报道了邻菲啰啉与四氧嘧啶稀土三元化合物的合成方法,通过对组成分析、红外光谱,核磁共振谱、热谱、磁矩和电子光谱等性质确定化合物的组成为 RE·HA·A(phen)1·5·C2H5OH·H2O(RE=La、Ce、Pr、Nd、H2A 为四氧嘧嘧,phen 为邻菲哕啉)RE·HA·A(phen)0·5·C2H5OH·2H2O(RE=Sm、Eu、Gd、Dy、Ho、Er、Yb、Y).药理实验表明,稀土三元化合物具有较强的抑菌作用.
【Abstract】 In this paper we report the method of preparation of a series of rare earth compounds with alloxan(H2A)and 1,10-phenanthroline(phen)inethanol-water solution.As determined by chemical analysis and elementalanalysis the compositions of these compounds are RE·HA·A(phen)1·5·C2H5OH·2H2O(RE=La,Ce,Pr,Nd)and RE·HA·A(phen)0·5·C2H5OH.2H2O(RE=Sm,Eu,Gd,Dy,Ho,Er,Yb,Y).Their solubilities and molarconductance,effective Bohr magneton number,IR,NMR,TG-DTA curves,electronic spectrum have been measured.The antibacterial results showthat these rare earth compounds have a strong antibacterial action.
【Key words】 rare earth compound; synthesis; analysis; 1,10-phenantroline; aiioxan; antibacterial action;
- 【文献出处】 兰州大学学报 ,Journal of Lanzhou University , 编辑部邮箱 ,1990年04期
- 【被引频次】9
- 【下载频次】44