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PREPARATION AND CHARACTERIZATION OF Kn[Z(H2O) CrW11 O39]·XH2O

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【作者】 吴庆银王恩波周延修

【Author】 WU QING-YIN(Shenyang Institute of Chemistry and Engineering, Shenyang 110021, PRC)WANG EN-BO AND ZHOU YAN-XIU(Department of Chemistry, Northeast Normal University, Changchun 130024, PRC)

【机构】 Shenyang Institute of Chemistry and EngineeringShenyang 110021PRCDepartment of ChemistryNortheast Normal UniversityChangchun 130024PRC

【摘要】 <正> The synthesis of new types of heteropoly compounds is an important aspect in the basic studies on heteropoly acidic catalysts. The ternary heteropoly compounds formed by substituting transition metals for tungsten in 12-heteropoly compounds remain Keggin struc ture with excellent catalystic activity. However, potassium 11-tungstochromate containing transition metals has not been reported. We synthesized Kn[Z (H2O)Cr W11 O39] XH2O (Z=Fe3+, Co2+, Ni2+ and Zn2+) by an improved method. The product was characterized by chemical analysis, ion-exchange, IR, UV and XPS.

【基金】 Project supported by the National Natural Science Foundation of China.
  • 【文献出处】 Chinese Science Bulletin ,科学通报(英文版) , 编辑部邮箱 ,1990年24期
  • 【下载频次】27
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