【摘要】 本文用β,β′-双环戊二烯基乙醚二钠与TiCl₄,ZrCl₄,（C₅H₅）TiCl₃和FeCl₂在四氢呋喃中反应合成了新型氧桥环戊二烯基钛、锆和铁衍生物.在企图合成硫桥环戊二烯基化合物时,得到的却是四亚甲基桥联双环戊二烯基金属衍生物。（苯二亚甲基）双环戊二烯基二钠与FeCl₂反应合成了对、间（苯二亚甲基）二茂铁.讨论了新化合物的X射线光电子能谱和Mossbauer谱。更多还原

【Abstract】 Ring-oxadiethylene bridged bis（cyclopentadienyl） chlorides and fluorides of titanium and zirconium were synthesized from the reaction of the disodium salt O（CH₂CH₂C₂H₄Na）₂ with TiGl₄, ZrCl₄, （C₅H₅）TiCI₃, and FeCl₂ in THF. A similar reaction of the sulfur analog gave only the product of tetramethylene bridged bis（cyclopentadienyl）dititanium halides. Ring-phenylene dimethylene bridged ferrocene was synthesized from the disodium salt p-, m-C₆H₄ （CH₂C₅H₄Na）₂ with FeCl₂. The XPS and Mssbauer spectra of some compounds were discussed.更多还原