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液体蒸汽向单气泡中传质过程的数值分析

Diffusion of Solvent Vapor in a Foreign Gas Bubble

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【作者】 杨宁生沈自求马英妮

【Author】 Yang Ningsheng, Shen Ziqiu and Ma Yingni(Dalian University of Technology, Dalain)

【机构】 大连理工大学化学工程研究所大连理工大学化学工程研究所 大连大连大连

【摘要】 <正>当气体通过液相介质时,由于气液界面和气相主体间存在液体蒸汽的浓度差,使液体迅速蒸发,可以大大强化对流传热及沸腾传热.此外,在鼓泡设备中,这种溶剂汽化现象亦可能对气含率及传质带来很大影响.因此,定量地分析液体蒸汽向气泡中传质的过程是很有意义的.此过程为具人体积变化的自由边界问题.对于核状沸腾过程的自由边界问题已有很多研究,其气泡长大的控制步骤为兴高采烈相可能提供的气化潜热速率,而由于气泡中质量传递控制的移动边界问题尚未见有研究.本文提出了液体溶剂向单气泡中传质的数学模型,获得了数值解.并且对各种影响因素进行了讨论.

【Abstract】 The diffusion process of liquid vapor in a gas bubble has been investigated numerically. With the assumptions of (1) spherical gas bubble; (2) constant temperature at gas-liquid interface; (3) no circulation inside the bubble, the mass transfer equation is developed as:Initial conditionsC(r, 0)=C0 Boundary conditionsC(R, t)=Cf It is also assumed that the pressure within the bubble is in equilibrium withambient pressure during the bubble growthA stepwise approach has been proposed to solve the moving boundary problem.The results show that Dt/R02 and Ps/P are the main factors for the dynamics of bubble growth. Generally speaking, increasing liquid temperature Tc and diffusitivity D, or reducing the ambient pressure P and initial bubble radius R0 favor the mass transfer, especially as PS/P→1, the enhancement of mass transfer is more obvious.

【基金】 国家自然科学基金
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,1990年01期
  • 【被引频次】2
  • 【下载频次】117
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