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氯铂酸与苯并-15-冠-5冠醚固态配合物的合成与性质
Synthesis and Properties of Chloro-Platinic Acid with Benzo-15-Crown-5 Crown Ether Solid Complexes
【摘要】 氯铂酸与苯并-15-冠-5(L)固态配合物经元素分析、红外光谱、紫外光谱、热谱、X-射线粉末衍射分析证明,此固态配合物是1∶2型(H2PtCl6·2L)分子间化合物.同时,结合核磁共振谱,讨论其可能的分子结构,并测试其溶解性和摩尔电导.
【Abstract】 The syntheses and properties of chloroplatinic acid with benzo-15-crown-5 crown ether solid complex is studied. It is a new kind of crown ether coordination compound, which is of 1∶2 type and identified by element analysis, IR spectrum, UV spectrum, TG DTA and X-ray. Its solubility have been detected. The molecular structure of this compound have been studied by NMR spectrum.
【关键词】 铂配合物;
合成;
性能;
冠式化合物;
【Key words】 Platinum complex; Synthesis; Properties; Crown ether compounds;
【Key words】 Platinum complex; Synthesis; Properties; Crown ether compounds;
- 【文献出处】 贵金属 ,Precious Metals , 编辑部邮箱 ,1990年03期
- 【被引频次】1
- 【下载频次】51