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载体及活性组份对聚合物负载铑络合物的催化醛化性能和稳定性的影响
THE EFFECT OF THE SUPPORTS AND ACTIVE SPECIES ON THE REACTIVITY AND STABILITY OF POLYMER-SUPPORTED RHODIUM COMPLEXES IN HYDROFORMYLATION
【摘要】 本文研究了载体和活性组份(包括载体交联度、孔径、比表面及铑负载量等因素)对聚合物负载铑络合物在己烯-1氢甲酰化反应中的催化性能与稳定性的影响。
【Abstract】 Effects of supports and active sepcies, including the degree of croslinking, specific surface area, pore radius of supports and the loading of rhodium etc., on the catalytic properties and stability of polymer-supported rhodium complexes in hydroformylation of 1-hexene were studied under batch reaction conditions. From the experimental results, it was found that these factors show certain influence on rhodium elution.
【基金】 国家自然科学基金
- 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,1990年05期
- 【被引频次】3
- 【下载频次】31