【摘要】 本文研究了过氧化氢在二甲基甲酰胺中的热分解反应,测定了不同温度下的分解速率常数和表现活化能。同时研究了过氧化氢引发丙烯腈的聚合反应,确定了聚合动力学方程。更多还原

【Abstract】 The thermal decomposition of hydrogen peroxide in DMF and the polymerization of acry-lonitrile initiated by hydrogen peroxide were studied. The rate constants and activation energy of thermal decomposition of hydrogen peroxide in DMF were determined. And from the kinetic data measurments of the polymerization of acrylonitrile in DMF at 105℃, the polymerization rate equation of acrylonitrile was presented asRp=K[H2O2]0.39[AN]1.85更多还原