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乙酸-水-甲酸体系的分离研究——酯化-共沸蒸馏精制醋酸
A Study on Separation of Acetic Acid,Water and Formic Acid System——Refinement of Acetic Acid by Esterification-Azeotropic Distillation
【摘要】 以乙酸-水-甲酸三元体系为研究对象,适当选择甲酸的酯化剂,进行该体系的分离实验。结果表明,用酯化-共沸蒸馏可除去乙酸、水和甲酸混合液中的水和甲酸,从而达到精制醋酸的目的。
【Abstract】 Separation for the acetic acid-water-formic acid system in a continuous distillation column was studied. The suitable esterification reagents for the dehydration of acetic acid and for removing formic acid from the system are saturated aliphatic alcohols containing 3- 6 carbon atoms. The experimental results obtained indicate that the acetic acid with a higher purity (>9 8. 5%) can be obtained by esterification-azeotropic distillation for the given system.
【关键词】 乙酸-水-甲酸体系;
酯化;
分离;
共沸蒸馏;
【Key words】 Acetic acid-water-formic acid system; Esterification; Separation; Azeotropic distillation;
【Key words】 Acetic acid-water-formic acid system; Esterification; Separation; Azeotropic distillation;
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1990年11期
- 【被引频次】4
- 【下载频次】278