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黄原胶分子量的研究
A Study of the Molecular Weight of Xanthan
【摘要】 <正> Dintzis曾用经典光散射法测得经90℃、4 mool/L尿素处理3h的黄原胶分子量为2×106,不加热的分子量为13×106和50×106,但未知确切数据.Rinaudo和Milas以相同的方法在l×10-3~l mool/L的氯化钠溶液中测得黄原胶的分子量为2×106.Southwick用动态光散射法在4 mol/L尿素中测出其分子量为2.16×106.G Holzwarth用透射电镜测出分子量为4×106~20×106之后,他又通过测定沉降系数和特性粘数,由MFS等式算出黄原胶原始分子量为15×106.可见,虽然实验方法和样品不同,但仍可确定其分子量在2×10650×106之间。
【Abstract】 The methods of ultracentrifugation, measuring molecular length by transmissive electron-microscope and small angle laser light-scattering were used to determine the molecular weight of self-made xanthan. The molecular weight measured by the three methods above are 2. 5×106, 6×106-2. 5×106 and 2. 36×106 dalton, respectively. Three results are well consistent with each other.
【关键词】 黄原胶;
分子量;
超速离心;
透射电镜;
小角激光散射;
【Key words】 Xanthan; Molecular weight; Ultracentrifugation; Transmissive electron- microscope; Small angle laser light-scattering;
【Key words】 Xanthan; Molecular weight; Ultracentrifugation; Transmissive electron- microscope; Small angle laser light-scattering;
【基金】 国家自然科学基金
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1990年07期
- 【被引频次】13
- 【下载频次】242