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多波长数据线性组合分光光度法及其应用

The Linear Combination of Spectrophotometry of Multi-Wavelength Data and Its Applications

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【作者】 李梦龙石乐明刘曙琼李志良俞汝勤

【Author】 Li Menglong, Shi Leming, Liu Shuqiong, Li Zhiliang, Yu Ruqin (Chemical and Chemical Engineering Department, Hunan University, Changsha)

【机构】 湖南大学化学化工系湖南大学化学化工系

【摘要】 基于吸光度联立方程组并选择一组合适的系数进行线性组合,提出了多波长吸光度数据线性组合分光光度法,得到的吸光度与被分析物浓度成正比,而与另一干扰物无关,从而消除干扰,本法能改善选择性与准确度,并具有测量波长较多与计算简便等特点,可用于两组分的单一或同时测定,已用于盐酸氯丙嗪与盐酸异丙嗪复方药物、雷琐辛复方涂剂等分析。

【Abstract】 The linear combination of multi-wavelength data (absorbance) is developed as a new computational spectrophotometry to improve the selectivity and accuracy, based on the combination of simultaneous equations with a set of proper coefficients. The absorbance obtained is in proportion to the concentration of the analyzed compounds and independent of the interferents, thus the in terference’ can be removed. The proposed method , which has the advantage for determining multi-wavelength data with simpler computation and can be used in single or simultaneous measurement, has been applied to the analysis of compound pharmaceutical preparations.

【基金】 国家自然科学基金
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1990年07期
  • 【被引频次】5
  • 【下载频次】43
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