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用SG树脂柱色谱法分离测定金矿中微量金
Determination of Gold in Ores by Preconcentration With SG Chelating Resin
【摘要】 SG树脂是我们合成的以交联聚苯乙烯为骨架,以胍基为功能团的新型树脂。本文针对矿样分析及柱色谱分析的要求,进行了淋洗液选择、淋洗速度、上柱流速、王水浓度及干扰离子影响等条件实验。并作了模拟金矿的合成样及四种金矿的测定,得到满意的分析结果。
【Abstract】 A new type of SG chelating resin containing quanidine as functional group was synthesized. Several optimum conditions for concentrating and separating gold from base metal by SG resin column chromatography were investigated. Golb can be absorbed by SG resin in a wide range of 0. 1~6 mol/L HCl and separated from base metal in lmol/L HCl. A solution of 90% actone-5% HC1一5%H2O was chosen as the best elucnt for Au(Ⅲ). Several gold ores were analyzed with good results.
【关键词】 胍基树脂;
柱色谱;
金;
金矿测定;
【Key words】 Quanidine chelating resin; Column chromatogarphy; Preconcentration; Gold ores; Gold;
【Key words】 Quanidine chelating resin; Column chromatogarphy; Preconcentration; Gold ores; Gold;
- 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1990年11期
- 【被引频次】9
- 【下载频次】36