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煤烟灰中多环芳烃的气相色谱/质谱分析
Gas Chromatographic/Mass Spectrometric Analysis of Polycyclic Aromatic Hydrocarbons in Coal Soot
【摘要】 用索氏抽提后硅胶柱层析法将煤烟灰中的有机物预先分离为脂肪烃、芳香烃和极 性化合物三种馏分,经气相色谱/质谱分析,从水平管式煤气发生炉和蒸汽机车烟灰 中分别检测出17种(183.58μg/g)和12种(95.41μg/g)致癌性多环芳烃化合 物,分别占芳香烃馏分的9.9%和12.2%,与大气漂尘的分析结果相近。
【Abstract】 By means of Soxhlet extraction, column separation and GC/MS detection, coal soal soot samples from gas generators and locomotive chimneys are are analyzed. The amount of carcinogenic PAHs are determined to be 185.58 and 95. 41 μg/g respectively. The PAHs amount to 72.9% of the total organic matterin boths amples of coal soot from gas generators and locomotive chimneys. The carcinogenic PAHs aocount for 9.9% and 12.2% of total PAHs in the former and the latter samples respectively.
- 【文献出处】 大连理工大学学报 ,Journal of Dalian University of Technology , 编辑部邮箱 ,1990年03期
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