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Fe-C-Si三元系熔体热力学

Thermodynamics of Fe-C-Si Ternary Melts at 1 450 ℃

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【作者】 俞荣祥冀春霖刘素兰张国范

【Author】 Yu Rongxiang,Ji Chunlin,Liu Sulan,Zhang Guofan

【机构】 东北工学院有色金属冶金系东北工学院有色金属冶金系

【摘要】 用银浴法在1450℃测定了两组Fe-C-Si合金熔体的等活度(αSi)数据,由此计算了活度交互作用系数εSiCSiC及ρSiSi,C;用Gibbs-Duhem方程积分计算了Fe-C-Si三元熔体的碳的活度系数lnγC

【Abstract】 Iso-silicon activity data for two sets of Fe-C-Si melt samples were determined by means of the common silver bath method at 1450℃. The experimental data were used to estimate the activity interaction coefficients εSiC, ρSiC and pSiSi,C in connection with the data of Fe-Si binary system determined in a previous work. The activity coefficient of carbon in Fe-C-Si ternary melt and its related activity interaction coefficients were calculated by the Gibbs-Duhem equation integration.

【关键词】 Fe-C-Si三元系热力学铁基熔体
【Key words】 Fe-C-Si meltthermodynamicsiron-based melt.
【基金】 国家自然科学基金
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