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用表面氧化处理改善 TiFe 合金的活化性能

ACTIVATING TiFe ALLOY FOR HYDROGEN SORPTION BY SURFACE OXIDATION TREATMENT

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【作者】 朱海岩陈长聘吴京王启东

【Author】 ZHU Haiyan;CHEN Changpin;WU Jing;WANG Qidong(Zhejiang University)

【机构】 浙江大学浙江大学

【摘要】 本文用空气中的放电氧化处理,改善了 TiFe 合金的表面活性,使 TiFe 合金在常温下活化。空气中的放电氧化处理使 FeTi 合金表面形成了一系列不同性质的氧化物,产生了有利于氢化学吸咐的新的催化中心。

【Abstract】 It is difficult to activate TiFe alloy for hydrogen sorption.In this report amicro-electric-arc oxidation treatment was developed and it was found that TiFe alloycould be activated at the room temperature by such a surface oxidation treatment.It is be-lieved that the surface oxidation treatment broke the inert oxide film on the original surfaceand produced a series of new oxides with different compositions,structures and chemicalstates,which provide new catalytic centers for dissociatve hydrogen chemisorption.

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