节点文献

常压低温下棉籽油催化加氢的研究

STUDY ON THE HYDROGENATION OF COTTON-SEED OIL UNDER ATMOSPHERIC PRESSURE AND LOW TEMPERATURE

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 温绍国; 王文祥; 张儒林;

【Author】 Wen Shao-guo, Wang Wen-xiang (Department of Chemistry, Zhengzhou University)and Zhang Ru-lin (Laboratory Center, Henan Academy of Agricultural Sciences, Zhengzhou)

【机构】 郑州大学化学系; 郑州大学化学系; 河南省农业科学院测试中心 郑州机械专科学校磨具磨料工程系化学组; 郑州;

【摘要】 以国产活性炭为载体制备筛选出的一种Pd/C催化剂,对棉籽油进行了加氢。结果表明:该催化剂具有相当高的活性和选择性及相当长的使用寿命。催化剂在30℃,钯/油比0.25%,常压下1小时可使棉籽油固化,固化油熔点约29℃。选择性(1小时)S2.1=12。催化剂可重复使用4次。本文还考察了温度、催化剂用量等对棉籽油氢化的影响,探讨了制备不同氢化程度、不同组成的氢化油产品应选取的操作条件。

【Abstract】 A Pd/C catalyst of high activity and selectivity for the hydrogcnation of raw cotton-Seed oil at low temperature and atmospheric pressure was prepared with a domestic active carbon as support. The cotton-Seed oil could be Solidified by hydrogenation in ethyl alcohol at 30℃ and a Pd/oil ratio of 0.25% in one hour. The melting point of the hardened oil was about 29℃. The selectivity S2.1 of the catalyst at 50℃in one hour was 12. The catalyst could be used repeatedly for more than four times. The effects of temperature, solvent and catalyst amount on the hydrogenation were studied. The suitable reaction conditions for preparing various hydrogenated oil products were also discussed.

  • 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,1990年02期
  • 【被引频次】2
  • 【下载频次】61
节点文献中: 

本文链接的文献网络图示:

本文的引文网络