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新甾醇Echifloristerol的结构测定
Structure Determination of Echifloristerol
【摘要】 从中国南海采集的花刺柳珊瑚中分离到一种新的甾醇echifloristerol。通过波谱方法,确定其结构为22-ξ-甲基-Δ5(6).23(24))-胆甾烷-3β-醇。
【Abstract】 A new marinc C28-sterol, Echifloristerol, was isolated from a Chinese gorgo- nia Echinogorgia Floria(Nutting) collected in Naozhou island. The crude acet one extract was separated on a silica gel column and eluted with petroleum ether containing increasing amounts of acetone. The crude echifloristerol obtained from petroleum ether-7% acetone eluted portion was recrystallized from ethyl acetate to give colorless plate crystal with m. p.136~137℃. On the basis of spectral analysis, the structure of echiforisterol was assigned as 22 ξ-methyl Δ3(6)23(24) cholestane-3β-ol I.
【基金】 国家自然科学基金资助项目
- 【文献出处】 中山大学学报(自然科学版) ,Acta Scifntiarum Naturalium Universitatis Sunyaatseni , 编辑部邮箱 ,1989年04期
- 【被引频次】5
- 【下载频次】46