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Cu-Cr Cu-Ti双层薄膜离子束混合与其电阻和硬度性质

ION BEAM MIXING OF Cu-Cr Cu-Ti BILAYER THIN FILMS AND ITS EFFECT ON HARDNESS AND RESISTANCE

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【作者】 施立群; 李梅林; 杨乃恒; 孙树滋;

【Author】 Shi Liqun (Hefei Polytechnic College, Beijing Laboratory of Vacuum physics, Academia Sinica) Li Meilin, Yang Naiheng, Sun Shuzi (Northeast University of Technology, Beijing Laboratory of Vacuum Physics, Academia Sinica)

【机构】 合肥工业大学、中国科学院北京真空物理实验室; 东北工学院、中国科学院北京真空物理实验室; 东北工学院、中国科学院北京真空物理实验室;

【摘要】 借助于透射电子显微镜(TEM)研究了Cu-Cr、Cu-Ti双层离子束混合。分别用200keVAr+和350keVXe+注入Cu-Cr、Cu-Ti双层薄膜,对其混合后的表面硬度和电阻进行了测量。发现Cu-Cr双层混合,在1017/cm2Ar+注入剂量时,TEM形貌图出现了沟纹,为一离子择优溅射效果,此时形成了单一的Cu基亚稳相固溶体,经200℃退火后,有孪晶生成,Cr沉淀析出,而Cu-Ti双层离子束混合有Cu3Ti2相生成,在400℃退火时生成了Cu3Ti相。离子束混合的表面硬度和电阻都有了显著地增加。经100~400℃退火,其表面硬度和电阻的变化主要受退火前混合程度、热处理引起的相变及损伤程度的综合影响。

【Abstract】 Ion beam mixing of Cu-Cr Cu-Ti bilayer thin films was investigated by means of transmission electron microscopy (TEM). The surfaee hardness electrical resistance of these films implanted respectively with 200 keV Ar+ and 350 keV Xe+ ion beams were measured. It is found that at a dose of 1017 Ar+/cm2 grooved formation occurred in the micrograph of Cu-Cr mixing due to selective spattering, and single met astable solution based on Cu is formed, After annealing microtwin and Cr precipitates. Whereas Cu3Ti2 is formed in Cu-Ti bilayered mixing, Cu3Ti formed by 400℃ annealing. The surface hardness and resistance of these films by ion mixing remarkable increaseel, After annealing at 100~400℃, these variations are mainly causeel by the resultant effects of the implantation before annealing, the phase transformation invoked by heat treatment and the recoverability from damage.

  • 【文献出处】 真空科学与技术 ,Vacuum Science and Technology , 编辑部邮箱 ,1989年04期
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