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某些含PrCl₃的二元氯化物相图及其热力学性质的评估和优化

ASSESSMENT AND OPTIMIZATION OF THE PHASE DIAGRAMS AND THERMODYNAMIC DATA OF SOME BINARY SYSTEMS CONTAINING PRASEODYMIUM CHLORIDES

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【Author】 Qiao Zhiyu, Wang Mingsheng, Zheng Chaogui~*, Duan Shuzhen (University of Science & Technology Beijing) Department of Chemisty Peking University

【机构】北京科技大学理化系；北京大学化学系；北京科技大学理化系；

【摘要】本文评估和优化了PrCl₃-MCl（M为Li、Na）,PrCl₃-MCl₂（M为Mg、Ca、Sr、Ba）六个二元系相图和热力学性质。经过评估和优化,具有热力学上自相一致性的二元相图和热力学性质是计算多元相图的基础。更多还原

【Abstract】 In this paper a critical assessment and optimization of the phase diagrams and thermodynamic properties of the PrCl₃-MCl₃（M:Li, Na） and PrCl₃-MCl₂（M:Mg, Ca, Sr, Ba） binary systems have been performed. The assessed and optimized binary phase diagrams and thermodynamic data With self consistency are a better basis for constructing multicomponent phase diagrams.更多还原