【摘要】 本工作利用X射线衍射分析、电导测量、红外、喇曼散射等手段,对用熔盐电解法生长的K_xWO₃,Na_yWO₃和K_xNa_yWO₃单晶进行了深入的研究,得出K_xNa_yWO₃是钠离子插入到K_xWO₃的结论,提出了K_xNa_yWO₃中离子扩散的机理.更多还原

【Abstract】 KxWO₃,NayWO and KxNayWO crystals were prepared by fused salt electrolysis. The X-ray diffraction, Raman, Infra-red we may conclude and condutivity me. asurements were made. From our results that KxNayWO3 is formed by intercalating Na+ ions into the tetragonal KxWO3 crystal lattice. A mechanism of ionic conduction is suggested.更多还原