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经不同温度热处理后铁交换沸石的穆斯堡尔谱分析

Analysis of Mssbauer Spectra of Iron-exchange-zeolite after Heat Treatment at Various Temperatures

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【作者】 吴泳华袁望志王大志丁力俞文海

【Author】 Wu Yonghua Yuan Wangzhi~(**) Wang Dazhi Ding Li~(***) Yu Wenhai (University of Science and Technology of China) ~(**)Engineering Institute of Guiyang.~(***)Chemical Engineering Institute of Jilin.

【机构】 中国科学技术大学贵阳工学院吉林化工学院中国科学技术大学 合肥合肥合肥

【摘要】 测量经不同温度热处理的铁交换沸石的穆斯堡尔谱,给出加热温度在600℃以下,沸石与β-FeOOH 共存,随着加热温度的升高沸石相的比例增加,并逐渐表现为非晶态。到600℃出现α-Fe2O3相,温度继续升高沸石相愈来愈少,加热温度为900~1000℃时沸石相不超过7%。

【Abstract】 We have measured the M(?)ssbauer spectra of iron-exchange zeolite heat-treatedat various temperatures.The results demonstrate that under 600℃ the zeolite coe-xists with β-FeOOH,the relative rate of zeolite rises with the increase in tempera-ture and gradually becomes amorphous,the α-Fe2O3 phase appears at 600℃,thezeolite phase is getting less and less as the temperature increases,and the zeolitephase does not exceed 7% between 900℃ and 1000℃.

【关键词】 沸石热处理穆斯堡尔谱
【Key words】 ZeoliteHeat treatmentM(?)ssbauer spectra
  • 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,1989年04期
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